Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts
Identifieur interne : 001101 ( Main/Exploration ); précédent : 001100; suivant : 001102Synthesis of new functionalized polyenes by cooligomerization of butadiene with methyl acrylate on nickel catalysts
Auteurs : A. Elamrani [Maroc] ; I. Suisse [France] ; A. Mortreux [France] ; N. Knouzi [Maroc]Source :
- Journal of Molecular Catalysis A: Chemical [ 1381-1169 ] ; 1995.
Abstract
New polyenes are formed in protic media via nickel catalyzed cooligomerization of butadiene with methyl acrylate. High activities are achieved with amino-phosphinite ligands in aprotic solvent. Using a deuterium labeled ligand, the presence of the NH group of the ligand is shown to be the key point for the proton transfer involved in the mechanism.
Url:
DOI: 10.1016/1381-1169(95)00085-2
Affiliations:
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<front><div type="abstract" xml:lang="en">New polyenes are formed in protic media via nickel catalyzed cooligomerization of butadiene with methyl acrylate. High activities are achieved with amino-phosphinite ligands in aprotic solvent. Using a deuterium labeled ligand, the presence of the NH group of the ligand is shown to be the key point for the proton transfer involved in the mechanism.</div>
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